A Mechanistic Approach to Methylene Blue Sorption on Two Vegetable Wastes: Cork Bark and Grape Stalks

نویسندگان

  • M. Àngels Olivella
  • Núria Fiol
  • Florencio de la Torre
  • Jordi Poch
  • Isabel Villaescusa
چکیده

Two vegetable wastes, cork bark and grape stalks, were investigated for the removal of methylene blue from aqueous solution. The effects of contact time, dye concentration, pH, and temperature on sorption were studied relative to adsorption on a commercially-activated carbon. The highest adsorption yield was obtained within the pH range 5 to 10 for grape stalks and 7 to 10 for cork bark. The sorption kinetics of dye onto activated carbon and grape stalks was very fast. Kinetics data were fitted to the pseudo-first and second order kinetic equations, and the values of the pseudo-second-order initial rate constants were found to be 1.69 mg g -1 min -1 for activated carbon, 2.24 mg g -1 min -1 for grape stalks, and 0.90 mg g -1 min -1 for cork bark. Langmuir maximum sorption capacities for activated carbon, grape stalks, and cork bark for methylene blue estimated by the Orthogonal Distance Regression method (ODR) were 157.5 mg g -1 , 105.6 mg g -1 , and 30.52 mg g -1 , respectively. FTIR spectra indicated that carboxylic groups and lignin play a significant role in the sorption of methylene blue. Electrostatic forces, n- interactions, cationand- stacking interactions contribute to methylene blue sorption onto grape stalks and cork bark. Grape stalks can be considered an efficient biosorbent and as a viable alternative to activated carbon and ion-exchange resins for the removal of methylene blue. 

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Evaluation Low Cost Adsorbent of Walnut Bark Granule for Methylene Blue Dye Removal from Aqueous Environments

Background & Aims of the Study: Methylene blue (MB) is a risk for human and environment. Adsorption process is one of the removal mechanisms of MB. The purpose of this research was the evaluation of low cost adsorbent of walnut bark granule for MB dye removal from aqueous environments. Materials & Methods: In this experimental research, the effect of various operating parameters...

متن کامل

Nickel Removal from Exhausted Electroplatting Baths by Using Vegetable Wastes

During the last years our research group has been studying the use of industrial vegetable wastes as grape stalks and exhausted coffee to remove metals ions such as Ni(II), Cu(II), Pb(II), Zn(II), Cd(II) or Cr(VI) and Cr(III) in aqueous solution from the point of view to use these wastes as biosorbents in a low cost alternative to activated carbon for wastewater treatment. The optimal experimen...

متن کامل

Effect of Temperature on Methylene Blue Sorption from Aqueous Solutions by Almond Peel: Experimental Studies and Modelling

In the present work, the influence of temperature on kinetics and equilibrium of methylene blue sorption from synthetic aqueous solutions, in single dye solutions, using almond peel as a sorbent material has been investigated in batch conditions. Temperature played an important part in sorption phenomenon: the methylene blue sorption increased as temperature increased. The pseudo second-order m...

متن کامل

Microwave-Hydrothermal Treated Grape Peel as an Efficient Biosorbent for Methylene Blue Removal

Biosorption using agricultural wastes has been proven as a low cost and efficient way for wastewater treatment. Herein, grape peel treated by microwave- and conventional-hydrothermal processes was used as low cost biosorbent to remove methylene blue (MB) from aqueous solutions. The adsorption parameters including the initial pH value, dosage of biosorbents, contact time, and initial MB concentr...

متن کامل

Prediction of Equilibrium Moisture Contents of Black Grape Seeds (Siah Sardasht cultivar) at Various Temperatures and Relative Humidity: Hhelf-Life Criteria

Background and Objectives: Food wastes are sometimes valuable; of which, seeds are significantly important. Grape seeds, as byproduct of grape processing, contain valuable substances for the production of advanced oils as well as feeds. Therefore, the major aim of this study was to assess moisture sorption isotherms of black grape seeds at various conditions. Materials and Methods: Moisture so...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2012